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Question Mixing Benzoic Acid
submitted almost 7 years ago by [deleted]

[deleted]

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7 points
 
by kindgroundalmost 7 years ago

If you bought salt nic it already has the benzoic acid added.

1 points
 
by devdoc9799almost 7 years ago

Oh so I don’t have to add additional benzoic acid? I thought juul juice has nicotine salts with extra benzoic acid added?

3 points
 
by Apexifiedalmost 7 years agoSuckling from the teats of Daenerys Targaryen

The benzoic acid is used to make the nicotine salts. They have several patents covering different methods but only seem to advertise one of them.

1 points
 
by devdoc9799almost 7 years ago

I called the guys who make the salts and they said there is no benzoic acid in their juice. I’m just asking if benzoic acid will dissolve in the eliquid I make or will I have to boil the mixture then add the acid so that it will dissolve?

3 points
 
by ClashOrCrashmanalmost 7 years ago

If your nic salt isn't made with benzoic acid, it's made with another acid. You aren't gonna convert one salt to another just by adding another acid to it. You'd have to start with freebase, and honestly my chemistry isn't sharp enough, but you'd need to know how much freebase you're converting and thus how much benzoic acid to get a complete conversion. You likely don't want to be vaping unreacted benzoic acid, but again, I'm not a chemist or a doctor.

2 points
 
by Roc77almost 7 years ago

Exactly. The acid is used purely to convert the free base to salt so there shouldn't be any left over. If there was it would cause a lower pH and impact the flavour profile. Titration can used to find out how much is needed to mop up all the base without residual acid left overs.

1 points
 
by devdoc9799almost 7 years ago

Yup exactly what I was thinking. I don’t think it’s a good idea. I’m kinda bummed now that I believe this juice won’t be as good as I thought. I wonder how close to juul juice I can get without making my own salts?

2 points
 
by ClashOrCrashmanalmost 7 years ago

I'm not sure where to buy it, but Chemnovatic's NicSalt-B is Nicotine Benzoate, so that'd be something to look into.

1 points
 
by devdoc9799almost 7 years ago

Alright awesome yeah I’m not trying to copy it exactly I just think the benzoic acid might be the most important part for the juice.

3 points
 
by grettledudealmost 7 years ago

You would add benzoic acid to freebase nicotine to get nicotine benzoate - that name literally means 'nicotine salt based on benzoic acid'. You already bought nicotine in salt form, so don't add more acid to it.

As for making the juice smoother, the acid makes freebase nic smoother by converting it to salt.

2 points
 
by devdoc9799almost 7 years ago

Clearest answer I’ve gotten all day. Thanks.

3 points
 
by grettledudealmost 7 years ago

I said the same thing as everybody else lol. But yeah, you should put the benzoic acid away, use the nicsalt solution as it comes and focus on getting the flavorings right. Good luck!

2 points
 
by devdoc9799almost 7 years ago

Thanks. Yeah I meant like you went and told me the proper terms which is pretty cool. Now I can probably sound like I know what I’m talking about. Haha.

1 points
 
by EdibleMalfunctionalmost 7 years agoMixologist

Sigh

2 points
 
by grettledudealmost 7 years ago

Did I say something wrong? Aren't nicsalts basically either nicotine benzoate or nicotine salicylate?

3 points
 
by EdibleMalfunctionalmost 7 years agoMixologist

No, you were fine. Just sighing because OP was told this multiple times

2 points
 
by EdibleMalfunctionalmost 7 years agoMixologist

Just use the nic salt

1 points
 
by devdoc9799almost 7 years ago

Dammit did I buy benzoic acid for no reason?

4 points
 
by EdibleMalfunctionalmost 7 years agoMixologist

More than likely.

1 points
 
by devdoc9799almost 7 years ago

Would it be a bad thing to add it to the mix anyways?

1 points
 
by madpianoalmost 7 years ago

You can treat acne with it?

1 points
 
by devdoc9799almost 7 years ago

Hey so I called the vendors of my salt nicotine and they told me there is no benzoic acid added to the salts. I’m not sure if you would know but would the acid mix with the solution and dissolve completely? Or would I need to heat it up or something?

5 points
 
by spbkaizoalmost 7 years ago

ask them what they have used. I'm guessing citric acid.

Note to people getting into this - once you start adding chemicals to other chemicals it's chemistry. That's a complex field.

Essentially this all depends on the acid you use, but given 1ml of 72mg nic base, add 54mg of benzoic acid. Heat to 60c for about an hour to allow it to protonate. While doing that, Google the word protonate.

3 points
 
by EdibleMalfunctionalmost 7 years agoMixologist

The acid is used to convert freebase to salts

2 points
 
by GreyDragon0almost 7 years ago

That sounds kinda janky to me

1 points
 
by devdoc9799almost 7 years ago

Ok so I just did some research and Benzoic Acid makes the hit smoother. It dissolves easier in PG than it does water. So I’m thinking about just adding it in and shaking it up for a couple minutes. And I ordered my salt nicotine from liquidnicotinewholesalers and when I called them they said that there is no benzoic acid in the salt nicotine. If this information doesn’t sound right to anybody let me know. The reason I am not testing this right now is because my materials did not come in yet.

2 points
 
by juthincalmost 7 years agoमैंगो कस्टर्ड

Ok... Some lesson time. I will dumb this down to what I suspect is the appropriate level. Nicotine exists in nature as a molecule known as a nicotine salt. Through chemical processing, this is converted to freebase nic which we use. This processing also is needed to purify the nic so we don't get contaminants. Freebase nic is a base, kinda like caustic soda. The throat prefers a more neutral-acidic pH range. For this reason, when acids are added to freebase nic, it is easier on the throat (aka smoother). Also, when you mix acid+freebase nic+ heat, you end up with a chemical reaction which forms nicotine salts. Numerous acids will work (but lsd probably won't) to form nicotine salts, although hydrobromic acid would be a poor choice. Adding more acid than is required will merely shift the pH of your finished juice, which may have a result in the taste, but is so long to have a few other effects on your respiratory system. However, a systematic test vaping.juices across a range of pH values would be a useful experiment for us to have results from.

0 points
 
by devdoc9799almost 7 years ago

So your saying I should have bought freebase nicotine to convert it to my own nic salt? Now I’m thinking I should have bought a pack of pods and a pH tester.

2 points
 
by juthincalmost 7 years agoमैंगो कस्टर्ड

If you wanted to add your own acid to most closely mimic Juul juices then yes. However, there was a post a while back where someone harvested the process from the patent filing... So no need to conduct tests on pods.

1 points
 
by isuamadogalmost 7 years ago

I don’t know, have you considered just vaping nic salts? At maybe a lower level than you’re used to and then getting used to it? Seems much more reliable in every way imo

0 points
 
by devdoc9799almost 7 years ago

I live on a college campus with everybody wasting money on juul pods. So I’m going to sell bottles of vape juice with the same concentrations as those juul pods. I also just want to make my own juice it sounds fun to me.

Edit: I’m privately selling them to my friends by the way. Not making a business out of it.

3 points
 
by EdibleMalfunctionalmost 7 years agoMixologist

Jumping the gun a bit aren't we?

1 points
 
by devdoc9799almost 7 years ago

What makes you say that?

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